A series of 1-alkyl- and 1-alkenyl-2,9,10-trioxatricyclo[4.3.1.0 3,8]decanes, models for the core orthoester structural moiety of resiniferatoxin and synaptolepis factors, was prepared by a transetherification reaction of (±)-all-cis-cyclohexane-1,2,4-triol and trimethyl orthocarboxylates. The synthesis of the starting trimethyl orthocarboxylates is also given in detail. © 2004 Published by Elsevier Ltd.
Synthesis of 1-substituted 2,9,10-trioxatricyclo[4.3.1.0 3,8]decanes
Rocchetti M. T.;
2004-01-01
Abstract
A series of 1-alkyl- and 1-alkenyl-2,9,10-trioxatricyclo[4.3.1.0 3,8]decanes, models for the core orthoester structural moiety of resiniferatoxin and synaptolepis factors, was prepared by a transetherification reaction of (±)-all-cis-cyclohexane-1,2,4-triol and trimethyl orthocarboxylates. The synthesis of the starting trimethyl orthocarboxylates is also given in detail. © 2004 Published by Elsevier Ltd.File in questo prodotto:
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